Ten properties and three special functions of titanium

Titanium is an element with atomic number 22 in the periodic table, a subgroup element of the fourth cycle, i.e., group IVB. In addition to titanium, elements of this group include zirconium and hafnium, which share the common feature of a high melting point and the formation of a stable oxide film on their surfaces at room temperature.

Top Ten Properties of Titanium
 

1, low density, high strength, high specific strength

Titanium's density is 4.51g/cm3, 57% of steel, titanium is less than two times heavier than aluminum, three times stronger than aluminum. Titanium alloy specific strength (strength / density ratio) is commonly used in industrial alloys in the largest (see Table 1), titanium alloy specific strength is 3.5 times that of stainless steel, aluminum alloy 1.3 times that of magnesium alloys, 1.7 times, so it is the aerospace industry is essential to the structure of the material.

 

Comparison of density and specific strength of titanium with other metals

Metal Titanium alloy Iron Aluminum (alloy) Magnesium (alloy) high-strength steel
Density 4.5 7.87 2.7 1.74 7.8
Specific Strength 29   21 16 23

 

Excellent corrosion resistance

The passivity of titanium depends on the presence of an oxide film, and it is much more resistant to corrosion in oxidizing media than in reducing media. High rate corrosion occurs in reducing media. Titanium does not corrode in some corrosive media, such as seawater, wet chlorine gas, chlorite and hypochlorite solutions, nitric acid, chromic acid, metal chlorides, sulfides, and organic acids. However, in media that react with titanium to produce hydrogen (e.g. hydrochloric and sulfuric acids), titanium usually has a large corrosion rate. However, if a small amount of oxidizing agent is added to the acid, a passivation film will form on the surface of titanium. Therefore, titanium is corrosion-resistant in strong sulfuric acid-nitric acid or hydrochloric acid-nitric acid mixtures, and even in hydrochloric acid containing free chlorine. The protective oxide film of titanium is often formed when the metal encounters water, even in small amounts of water or water vapor. If titanium is exposed to a strongly oxidizing environment in the complete absence of water, rapid oxidation occurs and violent reactions and even spontaneous combustion often occur. Such phenomena have occurred when titanium reacts with fuming nitric acid containing excess nitrogen oxide, and when titanium reacts with dry chlorine gas. Therefore, a certain amount of water is necessary to prevent such reactions.

good heat resistance

Usually aluminum at 150 ℃, stainless steel at 310 ℃ that is the loss of the original performance, and titanium alloy at 500 ℃ or so still maintain good mechanical properties. When the aircraft speed reaches 2.7 times the speed of sound, the surface temperature of the aircraft structure reaches 230 ℃, aluminum alloys and magnesium alloys can not be used, while titanium alloys can meet the requirements. Titanium's heat resistance is good, it is used for aero-engine compressor disk and blade and the skin of the rear fuselage of the aircraft.

Good low-temperature performance

Certain titanium alloys (such as Ti-5AI-2.5SnELI) strength with the reduction of temperature and increase, but the plasticity is not reduced much, in the low temperature still has good ductility and toughness, suitable for use in ultra-low temperature. Can be used in dry liquid hydrogen and liquid oxygen rocket engines, or in manned spacecraft for the use of ultra-low temperature containers and storage tanks.

Non-magnetic

Is Titanium Magnetic? of course not.Titanium is renowned for its non-magnetic attributes, stemming from its unique crystalline structure devoid of unpaired electrons, making it diamagnetic and impervious to magnetic fields. This intrinsic property ensures that titanium remains unaffected by magnetism, contrasting sharply with metals like iron, cobalt, and nickel, which possess unpaired electrons and exhibit magnetic characteristics when exposed to magnetic forces. The absence of magnetic interference makes titanium an exemplary choice for critical applications in medical devices, aerospace engineering, and chemical processing industries, where magnetic neutrality is crucial for operational integrity and safety. Although titanium alloys could show magnetic traits if contaminated with iron, pure titanium retains its non-magnetic quality, providing a reliable and stable material in environments where magnetic fields could pose risks or interfere with equipment performance. Thus, for industries that prioritize non-interference with magnetic fields, titanium offers unmatched advantages, combining strength, lightweight nature, and corrosion resistance with essential non-magnetic properties, ensuring both functionality and safety in sensitive applications.

Small thermal conductivity

A comparison of the thermal conductivity of titanium with other metals is shown in the following table

metal pure titanium titanium alloy Ordinary steel Stainless steel Al alloy Mg alloy Copper
Thermal Conductivity/W•(m•K)-1 17 7.5 63 16 121 159 385

 

The thermal conductivity of titanium is small, only 1/5 of that of steel, 1/13 of that of aluminum, and 1/25 of that of copper. poor thermal conductivity is a disadvantage of titanium, but this characteristic of titanium can be exploited in certain situations.

Low modulus of elasticity

Comparison of the modulus of elasticity of titanium with other metals

metal pure titanium titanium alloy Ordinary steel Stainless steel Al alloy Mg alloy Copper
Elastic Modulus/Gpa 106.3 113.2 205.8 199.9 71.5 44.8 107.8

The modulus of elasticity of titanium is only 55% of that of steel, and the low modulus of elasticity is a disadvantage when used as a structural material.

 

Tensile strength is very close to yield strength

Ti-6AI-4V titanium alloy tensile strength of 960MPa, yield strength of 892MPa, the difference between the two is only 58MPa, see the following table

Strength Titanium alloy
Ti-6al-4V
Titanium alloy Ordinary steel
Tensile strength 960 608 470
Yield strength 892 255 294

Titanium is easily oxidized at high temperatures

Titanium has a strong bond with hydrogen and oxygen, so it is important to prevent oxidation and hydrogen absorption. Titanium welding should be performed under argon protection to prevent contamination. Titanium tubes and thin plates should be heat treated under vacuum, and a slightly oxidizing atmosphere should be controlled during heat treatment of titanium forgings.

Low damping performance

Use titanium and other metal materials (copper, steel) to make bells of exactly the same shape and size. If you strike each bell with the same force, you will find that the sound of the titanium bell lasts longer when it vibrates, that is, the energy given to the bell by striking is not easy to disappear. Therefore, we say that titanium has low damping performance.

Three special functions of titanium
 

Shape memory function

This refers to the ability of Ti-50%Ni (atomic) alloy to recover its original shape under certain temperature conditions, calling this material a shape memory alloy.

Superconductivity

Refers to the Nb-Ti alloy, when the temperature drops to near absolute zero, Nb-Ti alloy made of wire, will lose resistance, any large current through, the wire will not heat, no energy consumption, Nb-Ti is known as superconducting materials

Hydrogen storage function

This refers to the Ti-50%Fe (atomic) alloy, which has the ability to absorb large amounts of hydrogen. Utilizing this feature of Ti-Fe, hydrogen can be stored safely, i.e., it is not necessary to use steel high-pressure cylinders to store hydrogen. Under certain conditions, Ti-Fe can also be used to release hydrogen, and Ti-Fe is called an energy storage material.

 

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